Product ID:LC16560, MANGANOUS SULFATE SOLUTIONS, (SUPDAT)
MSDS Date:02/23/1992
FSC:6810
NIIN:00N084084
MSDS Number: CGSDS

LABCHEM INC

200 WILLIAM PITT WAY
PITTSBURGH, PA 15238
US

Emergency Phone: 412-826-5230

Info Phone: 412-826-5230

Preparer: AL BERANEK

Cage: EO318

LABCHEM, INC.

PITTSBURGH, PA 15238 US

Telephone: 412-826-5230

Cage: 0MX47

0.05% TO 36.4%

CAS: 10034-96-5

RTECS: OP0893500

Fraction By Weight: <36.4%

OSHA PEL 5 MG MN/M3 CEILING

ACGIH TLV: 5 MG MN/M3

0.7

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: BALANCE

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION MAY CAUSE
RESPIRATORY TRACT, COUGH, MUSCULAR TWITCHINGS, MAY CAUSE IRRITATION
TO EYES AND SKIN. MANGANESE SALTS ARE POORLY ABSORBED, BUT MAY
CAUSE GASTRITIS, NAUSEA, DIARRHEA, AND HY POGLYCEMIA. CHRONIC:
INHALATION MAY LEAD TO BRONCHITIS, PNEUMONIA, HEADACHE, NUMBNESS OF
EXTREMITIES, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DERMATITIS, LIVER ENLARGEMENT.
REPEATED EXPOSURE MAY LEAD TO CONJUNCTIVITIS. INGESTION MAY CAUSE
SYMPTOMS OF SEVERE CENTRAL NERVOUS SYSTEM DISTURBANCES. TOX:
MANGANOUS SULFATE - 120 MG/KG IN TRAPERITONEAL-MOUSE LD50:
MUTAGENIC DATA (RTEC); TUMORIGENIC DATA (RTEC). MANGANOUS SULFATE
SOLN IS HIGHLY TOX (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: IF BRTHG HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. GET
MED AID AT ONCE. SKIN: REMOVE CONTAMD CLOTHING & FLUSH AREA W/LG
AMTS OF WATER FOR 15-20 MINS. GET MED AID AT ONCE. EYES: FLUSH W/LG
AMTS OF WATER FOR @ LST 15 MINS. GET MED AIDAT ONCE. INGEST: NO
SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET
MEDICAL AID AT ONCE.

Flash Point:NEGLIGIBLE
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY, FOAM.
Fire Fighting Procedures:NO ACUTE HAZARD. MOVE CONTAINER FROM AREA IF
POSSIBLE. AVOID BREATHING VAPORS. USE NIOSH APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE AND EXPLOSIVE HAZARD.

Spill Release Procedures:SOAK UP SPILL WITH VERMICULITE AND PLACE IN
SUITABLE CONTAINERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN CONTAINERS AWAY FROM HEAT.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR
WITH AN ORGANIC VAPOR CARTRIDGE. FIREFIGHTING - NIOSH APPRVD
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE.
Ventilation:PROVIDE GENERAL DILUTION VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
PROTECTIVE CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE NAME/PART NO: 0.003M AND 36.4%. EFTS OF OVEREXP: BY
INTRAPERITONEAL ROUTES, BUT IS POORLY ABSORBED THROUGH
INHAL/INGEST. CAUSES IRRIT TO EYES & MUCOUS MEMBRANES.

Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:<32F,<0C
Vapor Pres:14 @ 20C
Vapor Density:SEE ING 2
Spec Gravity:1.0-1.27
pH:4-7
Evaporation Rate & Reference:>1 (ETHER =1)
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR, PINK LIQUID/ODORLESS.

Stability Indicator/Materials to Avoid:YES
NONE REPORTED.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES.
Hazardous Decomposition Products:BY PRODUCTS: THERMAL DECOMPOSITION
PRODUCTS INCLUDE HIGHLY TOXIC OXIDES OF SULFUR.

Waste Disposal Methods:DISPOSE ACCORDING TO FEDERAL, STATE, AND LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.